A late goal by substitute Yordi Gonzalez earned Zaragoza a 1-1 draw and eliminated FC Barcelona in a Copa del Rey second-leg quarterfinal on Thursday.
Zaragoza advanced to the last four on a 2-1 aggregate score.
Yordi's 85th-minute strike leveled Barcelona forward Luis Garcia's 14th-minute goal to oust the Catalan club, which lost the first leg at its Camp Nou stadium 1-0.
The defeat is a massive blow for Barcelona as it hoped to win this year's competition to end a drought without a major trophy, which stretches back to 1999. Its only realistic hope of silverware this season now rests with the UEFA Cup, in which it has reached the last 16.
Zaragoza joins favorite Real Madrid, Sevilla and second-division Alaves in the draw for the semifinals. The games will be played over the next two weeks.
On Wednesday, Madrid eliminated Valencia 5-1 on aggregate, Sevilla knocked out Atletico de Madrid 6-1, while Alaves won through against Celta de Vigo 4-3.
Frank Rijkaard's Barcelona failed to take advantage of the good start provided by Garcia's goal, a spectacular volley from outside the area.
The early goal briefly boosted Barcelona, and goalkeeper Cesar Lainez made a good save to keep out Dutch striker Patrick Kluivert's goalbound shot nine minutes later.
Zaragoza suddenly burst into action in the 28th minute with forward David Pirri's fierce shot blocked by advancing Barcelona goalkeeper Victor Valdes, and Argentine midfielder Luciano Galletti hitting the post seconds later.
But Barcelona resumed control and Dutch midfielder Edgar Davids -- recently loaned from Juventus -- came close to netting his first goal for the club in the 34th with a low shot which was saved by Lainez.
However, Barcelona failed to live up to its promise in a second half which was short on incident as both sides struggled to create goal chances.
Barcelona's attacking power was hit when Kluivert was replaced by Argentine substitute Javier Saviola in the 51st after being injured by a tackle by Argentine defender Gabriel Milito.
Garcia came closest to giving Barcelona an aggregate lead with another volley in the 70th after Ronaldinho, who had been below his best, sprang to life with a surging run.
But following the Brazilian's replacement by midfielder Luis Enrique Martinez in the 77th, Barcelona lost its last hope of inspiration.
Barcelona's fate was sentenced five minutes from time when Milito headed back a corner and Yordi, a halftime substitute for striker Goran Drulic, volleyed home.
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